Process for terminating polyphenylene ethers reactions with amin

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 47CZ, 260 47CP, 260 49, C08G 6544

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active

040585042

ABSTRACT:
In the production of polyphenylene ethers by oxidative polycondensation of phenols in the presence of a complex catalyst, an aminocarboxylic acid derivative and a reducing agent are simultaneously added to the reaction mixture when the resulting polyphenylene ether has attained the desired degree of polymerization, thereby to terminate the polymerization and simultaneously purify the reaction mixture. Hence, a stable purified polymer can be obtained.

REFERENCES:
patent: 3573254 (1971-03-01), Factor
patent: 3787358 (1974-01-01), Nishioka et al.
patent: 3817919 (1974-06-01), Nakashio et al.
patent: 3843604 (1974-10-01), Pravednikov et al.
patent: 3951917 (1976-04-01), Floryan et al.

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