Process for synthesizing thiacyanine dyes

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548152, C07D41706

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active

042257050

ABSTRACT:
There is described a process for synthesizing a thiacyanine dye wherein a 2-halo, 2-alkoxy or 2-aryloxybenzothiazole is alkylated by a strong alkylating agent to form a quaternized benzothiazole which, without being isolated, is condensed with a benzothiazolium betaine in a nonaqueous homogeneous medium. The thiacyanine dye is useful for enhancing the photosensitivity of a blue-sensitive silver halide emulsion.

REFERENCES:
patent: 3149105 (1964-09-01), Larive et al.
patent: 4028353 (1977-06-01), Borror
Hamer, The Cyanine Dyes and Related Compounds, Interscience, N.Y., N.Y., 1964, pp. 46, 47, 58, 59.

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