Process for starting up a Fischer-Tropsch reactor

Chemistry: fischer-tropsch processes; or purification or recover – Temperature control or regulation of the fischer-tropsch...

Reexamination Certificate

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C518S705000, C518S728000

Reexamination Certificate

active

06974844

ABSTRACT:
A process for starting up a Fischer-Tropsch reactor includes establishing, in the reactor, an initial charge of molten wax. The initial reactor temperature is below the line-out reactor temperature but is sufficiently high for a Fischer-Tropsch reaction to take place. The reactor contains, in contact with the molten wax, at least a portion of its line-out catalyst inventory. Syngas is fed into the reactor at an initial flow rate below the line-out syngas flow rate. Initially a syngas H2:CO molar ratio is maintained at a higher value than its line-out value, whereafter the syngas H2:CO molar ratio is decreased to its line-out value. The syngas flow rate and the reactor temperature are then increased to their line-out values.

REFERENCES:
patent: 4626552 (1986-12-01), Arcuri
patent: 5389690 (1995-02-01), Mitchell
patent: 5780381 (1998-07-01), Wilson et al.
patent: 6512017 (2003-01-01), Steynberg et al.
patent: 1 004 318 (1952-03-01), None

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