Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction
Reexamination Certificate
2011-06-28
2011-06-28
Parsa, Jafar (Department: 1621)
Chemistry: fischer-tropsch processes; or purification or recover
Liquid phase fischer-tropsch reaction
C518S728000
Reexamination Certificate
active
07968610
ABSTRACT:
Process for maintaining the stability of performances of a catalyst for Fischer-Tropsch reaction, performed in a slurry bubble column reactor under a triphase system which comprises gradually increasing the PH2O/PH2ratio and the PH2O/Z ratio, during the start-up phase, with Z=P0·(T/T1)4·e−(K2/(t·K3))from 0.4 to 0.8, for a period of time not shorter than 100-150 hrs and not longer than 200-300 hours and, at the end of the start-up phase, maintaining the PH2O/PH2and PH2O/Z ratios substantially equal to or lower than 0.8.
REFERENCES:
patent: 2011/0009502 (2011-01-01), Marion et al.
Krishnamoorthy, Sundaram et al., “An Investigation of the Effects of Water on Rate and Selectivity for the Fischer-Tropsch Synthesis on Cobalt-Based Catalysts”, Journal of Catalysis, vol. 211, No. 2, pp. 422-433, XP002578680, (Oct. 25, 2002).
Bertole, J. Christopher et al., “The Effect of Water on the Cobalt-Catalyzed Fischer-Tropsch Synthesis”, Journal of Catalysis, vol. 210, No. 1, pp. 84-96, XP002578681, (Aug. 15, 2002).
Tavasoli, A. et al., “Raising Co/A12O3catalyst lifetime in Fischer-Tropsch synthesis by using a novel dual-bed reactor”, Fuel Processing Technology, vol. 88, No. 5, pp. 461-469, XP002578682, (May 2007).
Dalai, A.K. et al., “Review Fischer-Tropsch synthesis: A review of water effects on the performances of unsupported and supported Co catalysts”, Applied Catalysis A: General , vol. 348, No. 1, pp. 1-15, XP002578683, (Sep. 30, 2008).
Schanke, D. et al., “Study of the deactivation mechanism of A12O3-supported cobalt Fischer-Tropsch catalysts”, Catalysis Letters, vol. 34, No. 3-4, pp. 269-284, XP002578684, (Sep. 1995).
Hilmen, A.M. et al., “Study of the effect of water on alumina supported cobalt Fischer-Tropsch catalysts”, Applied Catalysis A: General, vol. 186, No. 1-2, pp. 169-188, XP002578685, (Oct. 4, 1999).
Claeys, Michael et al., “On the effect of water during Fischer-Tropsch synthesis with a ruthenium catalyst”, Catalysis Today, vol. 71, No. 3-4, pp. 419-427, XP002580229, (Jan. 15, 2002).
Zhang, Yulong et al., “Effect of Water Vapor on the Reduction of Ru-Promoted Co/A12O3”, Journal of Catalysis, vol. 188, No. 2, pp. 281-290, XP002578686, (Dec. 10, 1999).
Li, Jinlin et al., “Fischer-Tropsch synthesis: effect of water on the deactivation of Pt promoted Co/A12O3catalysts”, Applied Catalysis A: General, vol. 228, No. 1-2, pp. 203-212, XP002578687, (Apr. 30, 2002).
Van Berge, P.J. et al., “Oxidation of cobalt based Fischer-Tropsch catalysts as a deactivation mechanism”, Catalysis Today, vol. 58, No. 4, pp. 321-334, XP002578688, (May 26, 2000).
Pollesel Paolo
Rossini Stefano
Tasso Andrea
ENI S.p.A.
Institut Francais du Pe'trole
Oblon, Spivak McClelland, Maier & Neustadt, L.L.P.
Parsa Jafar
LandOfFree
Process for stabilizing the performances of a catalyst for... does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for stabilizing the performances of a catalyst for..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for stabilizing the performances of a catalyst for... will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2706082