Process for separation of traces of gaseous contaminants from wa

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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423224, 423240, 423241, 423245, 423242, 423491, 423493, 423561R, 210760, 204130, B01D 5334, B01D 5700

Patent

active

043703062

ABSTRACT:
In the separation of traces of halogens and sulfur from a halogen- and/or sulfur-containing gas stream wherein the gas stream is contacted with a wash liquid to absorb the halogens and sulfur, the improvement which comprises including in the wash liquid heavy metal ions capable of forming difficultly soluble halides and sulfides. Preferably the heavy metal ions are silver or copper, and the insoluble heavy metal sulfide and/or halide is removed from the wash liquid which is recirculated. Almost quantitative removal is achieved in as little as 1 second of gas-wash liquid contact.

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patent: 3852407 (1974-12-01), Schmitt et al.
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Biltz-Klemm-Fischer, "Experimentelle Eintohrung indie Anorganische Chemie", alter de Gruyen & Co., Berlin, 1971, pp. 111-115.
Ryland et al, "Thiols", The Analytical Chemistry of Sulfur and its Compounds, Part I, 1970, pp. 465-519, Wiley-Interscience, New York.
Moore et al., "A Spectrographic Method for the Determination of Mercaptans in Air", Industrial Hygene Journal, Dec. 1960, pp. 466-470.

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