Process for separation of naphthalenedisulfonic acids

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260505P, C07C14324

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active

043247423

ABSTRACT:
A process for separating 1,6-naphthalenedisulfonic acid, 2,6-naphthalenedisulfonic acid or 2,7-naphthalenedisulfonic acid selectively from reaction mixtures obtained by disulfonation of naphthalene under different reaction conditions is disclosed. For example, a particular disulfonation reaction of naphthalene is carried out which favors the formation of a particular isomer. This reaction mixture is diluted with water to adjust the sulfuric acid concentration to 35 to 90% by weight and the temperature is maintained at 0.degree. to 80.degree. C.; 1,6-naphthalene-disulfonic acid is selectively separated at high purity.

REFERENCES:
patent: 2125189 (1938-07-01), Lofton et al.

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