Process for separation and purification of dihydric phenols

Distillation: processes – separatory – With disparate physical separation – Utilizing removing solid from liquid

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203 73, 203 92, 568753, B01D 338, C07C 3908

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active

043081100

ABSTRACT:
Highly decolorized, purified hydroquinone and resorcinol can be separated from each other from a mixture containing hydroquinone and resorcinol and recovered by continuously rectifying the mixture, thereby obtaining rectification bottoms containing resorcinol and hydroquinone in a ratio by weight of resorcinol to hydroquinone of 0.1-1:1 while obtaining resorcinol as a distillate, redistilling the rectification bottoms, contacting hydroquinone vapor with water vapor, condensing the hydroquinone vapor in the presence of the water vapor, thereby recovering hydroquinone as an aqueous hydroquinone solution, and then recrystallizing the aqueous hydroquinone solution, if necessary, in the presence of an organic solvent, thereby separating hydroquinone from the aqueous solution.

REFERENCES:
patent: 1912628 (1933-06-01), Elliott
patent: 3900523 (1975-08-01), Tada et al.
patent: 3929910 (1975-12-01), Suda et al.
patent: 3968171 (1976-07-01), Burkholder et al.
patent: 4049723 (1977-09-01), Tanaka et al.
patent: 4119791 (1978-10-01), Hollingshead et al.

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