Process for separating zirconium isotopes

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423 70, C01G 2500, B01D 5900

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active

045841837

ABSTRACT:
A solvent extraction-exchange process for the enrichment of either the zirconium 90 isotope component or the zirconium 91-96 isotope component of an aqueous feed stream containing both components is described. An aqueous feed stream of zirconium complexes such as that from a thiocyanate separation process is contacted with an organic solvent to preferentially extract one of the isotope components, resulting in an aqueous raffinate enriched in the other isotope component. The organic phase is further contacted with an aqueous phase enriched in said one isotope component to exchange the other isotope component from the organic phase with the one isotope component in the aqueous phase and produce a further enriched organic phase. The one isotope component in the further enriched organic phase is then stripped with an aqueous acidic strip medium, and zirconium enriched in said one isotope component separated therefrom.

REFERENCES:
patent: 3069232 (1962-12-01), Greenberg et al.
patent: 4389292 (1983-06-01), Phillips et al.
K. Kogure et al., Journal of Chromatography, 259, (1983), pp. 480-486, Elsevier Sci. Pub. Amsterdam.

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