Process for separating the reaction products obtained from ether

Distillation: processes – separatory – Distilling to separate or remove only water – From organic compound

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203 84, 203 85, 203 97, 203 98, 203DIG19, 568699, B01D 334

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active

043349641

ABSTRACT:
A method for separating a mixture of reaction products produced in the catalytic etherification of a lower isoolefin with methanol wherein said reaction product comprises a mixture of ether, methanol, unreacted hydrocarbon and tertiary alcohol which comprises adding water to said reaction product to form a hydrocarbon phase containing said ether and an aqueous phase containing methanol and a tertiary alcohol, separating said hydrocarbon phase to recover a methyltertiary alkyl ether, introducing said alcohol-containing aqueous phase into a distillation column to separate a methanol fraction overhead, withdrawing a side stream rich in tertiary alcohol from said distillation column, stripping this side stream in a stripping column to separate a second methanol fraction overhead and a tertiary alcohol bottoms fraction and recycling the methanol overhead fraction from the stripping column to the upper part of the distillation column and recycling the overhead methanol fraction from the distillation column to the feed stream to said reactor.

REFERENCES:
patent: 3846088 (1974-11-01), Brown et al.
patent: 4144138 (1979-03-01), Rao et al.

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