Process for separating methanol from the reaction products obtai

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568699, 568913, 203 43, 203 71, 203DIG6, 203DIG19, C07C 4138, C07C 4142

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active

045447764

ABSTRACT:
The reaction product from etherification of C.sub.4 -C.sub.7 isoolefins with methanol in the presence of an acidic catalyst is washed with water in the presence of inert hydrocarbons thereby removing methanol and a part of the tertiary alcohol. The aqueous extract solution bottoms is distilled to separate methanol as overhead. Tertiary alcohols are withdrawn as a side stream from a tray of the distillation column with a high concentration thereof and fed into the washing column.

REFERENCES:
patent: 4144138 (1979-03-01), Rao et al.
patent: 4302298 (1981-11-01), Mikitenko et al.
patent: 4324924 (1982-04-01), Torck et al.
patent: 4334964 (1982-06-01), Prezelj et al.

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