Process for separating isomers of disubstituted benzenes and age

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.

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585833, 585865, 564424, 570190, 570211, C07C 700, C07C20900, C07C 1700

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active

051773023

ABSTRACT:
This invention is concerned with a process for separating isomers of disubstituted benzenes, wherein a mixture of isomers of disubstituted benzenes is contacted with a substituted cyclodextrin to form inclusion complexes, and desired isomers are recovered therefrom in a highly selective manner. The invention also provides substituted cyclodextrins suited for use in the process. Substituted cyclodextrins used in the process can be recovered and used repeatedly.

REFERENCES:
patent: 3456028 (1969-07-01), Gerhold et al.
patent: 5095173 (1992-03-01), Uemasu et al.
Staerke, vol. 39, No. 10, Oct. 1987, Weinheim De, pp. 357-362; J. Szejtli: "Application of cyclodextrins in the chromatography", p. 358, paragraph 2.1, Germany.
Patent Abstracts of Japan, vol. 12, No. 426 (C-542) (3273) Nov. 10, 1988 of JP-A-63 154 703 (Nikken Kagaku), Jun. 28, 1988, Japan.

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