Process for selective separation of plutonium from uranium and o

Details Process for selective separation of plutonium from uranium and o Process for selective separation of plutonium from uranium and o

1983-06-29

1986-05-27

Miller, Edward A.

Chemistry of inorganic compounds

Treating mixture to obtain metal containing compound

Radioactive metal

423 3, 423251, C01G 5600

Patent

active

045914885

ABSTRACT:
A process for selectively separating plutonium from uranium and other metals is disclosed wherein, in order to precipitate and remove the pertaining complexes, use is made of a sufficient quantity of a cationic compound containing at least one group adapted to assert affinity to polar surfaces and containing a radical which has little affinity to water, e.g. surface active agents and the like, and use is made of the capability of Pu.sup.4+ and U.sup.4+ to form nitrato-complexes and of the capability of Pu.sup.4+ and UO.sub.2.sup.2+ to form sulfato-complexes.

REFERENCES:
patent: 2992888 (1961-07-01), Balthis
patent: 3195977 (1965-07-01), Matheson
patent: 4464343 (1984-08-01), Hitchcock et al.

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