Process for selective hydrogenation of C-C double bonds in the p

Details Process for selective hydrogenation of C-C double bonds in the p Process for selective hydrogenation of C-C double bonds in the p

1984-10-11

1987-06-16

Brust, Joseph Paul

Organic compounds -- part of the class 532-570 series

Organic compounds

Nitriles

558432, 558433, 558454, 558459, 558467, 564248, 564253, 564268, 568939, C07C12116, C07C12120, C07C13102, C07C13100

Patent

active

046737570

ABSTRACT:
Carbon-carbon double bonds are hydrogenated selectively in a compound containing a reducible, nitrogen-containing group if the hydrogenation is carried out in the presence of a ruthenium complex catalyst. Also disclosed are new ruthenium complexes for use in such selective hydrogenation.

REFERENCES:
patent: 3454644 (1969-07-01), Dewhirst
patent: 3488400 (1970-01-01), Candlin et al.
patent: 3489786 (1970-01-01), Dewhirst
Fieser et al., Reagents for Organic Synthesis, vol. 1 (1967) pp.983-986.
Fieser et al., Reagents for Organic Synthesis, vol. 8 (1980) pp. 159-160.
Bruce, et al., Aust. J. Chem., 30 (1977) pp. 1601-1604.

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