Process for selective formation of C.sub.4 compounds and thiol-c

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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Other Related Categories

568888, 568902, C07C 2722, C07C 4550

Type

Patent

Status

active

Patent number

043396100

Description

ABSTRACT:
C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:

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patent: 3387043 (1968-06-01), Kuraishi et al.
patent: 4133966 (1979-01-01), Pretzer et al.
patent: 4168391 (1979-09-01), Slinkard et al.
patent: 4171461 (1979-10-01), Bartish
patent: 4262154 (1981-04-01), Gane et al.

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