Process for selective bromination of para-alkylstyrene/isoolefin

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526135, 526196, 526237, 526347, 5263487, 526912, 5253334, 525355, 525356, 522160, C08F 214, C08F21208

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059590491

ABSTRACT:
A process for producing a copolymer of isoolefin having between 4 and 7 carbon atoms and para-alkylstyrene is provided. The process comprises admixing the isoolefin and the para-alkylstyrene in a copolymerization reactor under copolymerization conditions in the presence of a diluent, and a Lewis Acid catalyst, and maintaining the copolymerization reactor substantially free of impurities which can complex with the catalyst or copolymerize with the isoolefin or the para-alkylstyrene.

REFERENCES:
patent: 3145187 (1964-08-01), Hankey et al.
patent: 3455890 (1969-07-01), Davidson
patent: 3702842 (1972-11-01), Davis et al.
patent: 3786116 (1974-01-01), Milkovich et al.
patent: 3862265 (1975-01-01), Steinkamp et al.
patent: 3932371 (1976-01-01), Powers
patent: 3948868 (1976-04-01), Powers
patent: 3998713 (1976-12-01), Marek et al.
patent: 4074035 (1978-02-01), Powers et al.
patent: 4145190 (1979-03-01), Webb
patent: 4299931 (1981-11-01), Coran et al.
patent: 4548995 (1985-10-01), Kowalski et al.
patent: 4713423 (1987-12-01), Mohanraj et al.
patent: 4879353 (1989-11-01), Sanders et al.
patent: 4975496 (1990-12-01), Tigner et al.
patent: 5084522 (1992-01-01), Frechet
Jones, et al., "Isobutylene Copolymers of Vinylbenzyl Chloride and Isopropenylbenzyl Chloride", Journal of Applied Polymer Science, vol. V (16), pp. 452-459 (1969).
Sadykhov, et al., "Chloromethylation of an Isobutylene-Styrene Copolymer and Some of Its Chemical Reactions", Acerb. Neft. Khoz., 1979 (6)--pp. 37-39.
Harris, et al., "Block and Graft Copolymers of Pivalolactone . . . ", Macromolecules, 1986, 19, 2903-2908.
Sadykhov, et al., "Studies of Oxidative Thermal Degradation of Copolymers of Isobutylene with m- and p-methylstyrenes in a Solution of Mineral Oils", Uch. Zap. Azerb. Un. t. Ser. Khum., 1975 (304), 87-92.
Toman, et al., "Isobutylene Polymers and Copolymers with Controlled Structure", Appl. 78/7, 339, Nov. 10, 1978.
R. Cohen, et al., Macromolecules, 15, 370, 1982; Macromolecules, 12, 131, 1979; J. Polym. Sci.--Polym. Phys., 18, 2145-2148, 1980; J. Macromol. Sci. -Phys., B17 (4), 625, 1980.
J. P. Kennedy, et al., J. Appl. Polym. Sci., Appl. Polym. Sym., 30 (1977); J. Macromol. Sci., Chem., A3, 861 (1969); Adv. Polym. Sci., 14, 1 (1974).
A. W. Halasaa, et al., J. Polym. Sci., Part A1, 9, 139, (1971); and J. Polym. Sci., Chem. Ed., 14, 497, (1976).
B. W. Brooks, J. Polym. Sci., Part B5, 641 (1967).
Y. Minoura, et al., J. Polym. Sci., Part A1, 6, 2773 (1968).
Marcel Camps, et al., "Chloromethylstyrene: Synthesis, Polymerization, Transformation, Applications" in Rev. Macromol. Chem. Physics, C22(3), 343-407, (1982-83).
JMJ Frechet, "Chemical Modification of Polymers via Phase Transfer Catalysts" in Crown Ethers and Phase Transfer Catalysts in Polymer Science, edited by Matthews and Canecher and Published by Plenum Press, NY, 1984.
Jean-Pierre Montheard, et al., "Chemical Transformations of Chloromethylated Polystyrene" in JMS Rev., Macromol. Chem. Phys., C-28 (3&4), 503-592, (1988).
Macromolecular Reviews, vol. 2, pp. 74-83, Interscience Publishers, Inc. (1967), "Monomers Polymerized by Anionic Initiators".
Principles of Polymerization, Chapter 7, pp. 508-563, 2nd ed., G. Odian, J. Wiley & Sons, New York (1981), and the 290 references contained therein.
H.L. Finkbeiner, et al., "Polymerization by Oxidative Coupling", Chapter 15 in Polymerization Processes, C.E. Schildknecht, ed., with I. Skeist, Wiley-Interscience, New York (1977).
"Anionic Polymerization", ACS Symposium Series 166, p. 60, American Chemical Society (1981).

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