Plastic and nonmetallic article shaping or treating: processes – Reactive gas or vapor treatment of work – Work is organic material
Patent
1995-05-24
1997-05-20
Tentoni, Leo B.
Plastic and nonmetallic article shaping or treating: processes
Reactive gas or vapor treatment of work
Work is organic material
264340, B29C 7100
Patent
active
056309708
ABSTRACT:
A process for restoring the selectivity of high-flee-volume, glassy polymer membranes for condensable components over less-condensable components or non-condensable components of a gas mixture. The process involves exposing the membrane to suitable sorbent vapor, such as propane or butane, thereby reopening the microvoids that make up the free volume. The selectivity of an aged membrane may be restored to 70-100% of its original value. The selectivity of a membrane which is known to age over time can also be maintained by keeping the membrane in a vapor environment when it is not in use.
REFERENCES:
patent: 5281255 (1994-01-01), Toy et al.
Yampol'skii et al., "Transport Characteristics and Other Physicochemical Properties of Aged Poly(1-(trimethyl)-1-propyne)" Jour. of Polymer Sci. 48, pp. 1935-1944. (1993).
Odani et al., "Design of Polymer Membranes for Gas Separation" in Polymers for Gas Separation, pp. 132-135, N. Toshima(Ed.), New York, (1992).
Nakagawa, T. et al. "Polyacetylene Derivatives as Membranes for Gas Separation", Gas Separation & Purification, vol. 2 (1988), pp. 3-8.
Casillas Carlos G.
Pinnau Ingo
Toy Lora G.
Farrant J.
Membrane Technology and Research, Inc.
Tentoni Leo B.
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