Process for removing sulfur particles from an aqueous...

Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur

Reexamination Certificate

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Details

C423S576200, C423S576400, C423S576500, C423S576600, C423S576700

Reexamination Certificate

active

11788738

ABSTRACT:
The invention relates to a process for removing hydrogen sulfide and recovering sulfur from a gas stream, comprising the steps of: contacting said gas stream with an aqueous catalyst solution of a polyvalent metal redox catalyst in a contacting zone to absorb said hydrogen sulfide and form a reduced catalyst solution comprising reduced polyvalent metal redox catalyst and sulfur particles; oxidizing said reduced catalyst solution while removing sulfur particles to form said oxidized aqueous catalyst solution comprising polyvalent metal redox catalyst in an oxidized state with sulfur particles removed; and recovering sulfur by transferring at least one of said sulfur particles and foam to a separation zone; wherein a coagulating reagent is added to a feed of said separation zone prior to entering said separation zone to promote settlement of sulfur particles.

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I. Iliuta, F. Larachi, “Concept of Bifunctional Redox Iron-Chelate Process for H2S Removal In Pulp and Paper Atmospheric Emissions,” Sep. 9, 2003, pp. 5305-5314, Chemical Engineering Science.

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