Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Halogenous component
Patent
1980-10-21
1982-05-11
Thomas, Earl C.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Halogenous component
423488, 570243, 570245, 570247, 570251, 570254, 570255, B01D 5336
Patent
active
043293239
ABSTRACT:
A process for removing ethylene and vinyl chloride from a gas stream containing them by passing a mixed gas containing ethylene, vinyl chloride and a necessary amount of chlorine through a fixed-bed reactor charged with as a catalyst an activated alumina supporting at least 4% by weight of ferric chloride in terms of iron, said catalyst having an outer surface area per unit packed catalyst volume of not less than 7.8 cm..sup.2 /ml. Ethylene and vinyl chloride are converted into and removed as 1,2-dichloroethane and 1,1,2-trichloroethane. The concentrations of ethylene and vinyl chloride can be decreased to not more than 10 p.p.m. and not more than 20 p.p.m., respectively.
REFERENCES:
patent: 3190931 (1965-06-01), Laine et al.
patent: 3892816 (1975-07-01), Kister
patent: 4029714 (1977-06-01), Ziegenhagen et al.
Ibaraki Hironobu
Shiozaki Ken
Kanegafuchi Kagaku Kogyo & Kabushiki Kaisha
Thomas Earl C.
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