Process for reducing Zn consumption in zinc electrolyte purifica

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204119, C23B 510, C25B 1103

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active

044392885

ABSTRACT:
The present invention contemplates treating a zinc sulfate containing solution, especially a neutral leach filtrate with a reducing agent selected from ZnSO.sub.3, SO.sub.2 or mixtures thereof to substantially reduce the oxidant therein and to obtain a solution having a predetermined pH. Thus, in one embodiment of the present invention, a neutral leach filtrate containing an oxidant selected from permanganate and manganate ions and mixtures thereof is treated with a reducing agent selected from ZnSO.sub.3, SO.sub.2 or mixtures thereof in amounts sufficient to substantially reduce all the manganese ions present (permanganate and/or manganate) to the divalent state and to provide a zinc sulfate solution for electrodeposition of the zinc having a predetermined pH.

REFERENCES:
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patent: 1969567 (1934-08-01), Lee
patent: 3649180 (1972-03-01), McKay et al.
patent: 3655538 (1972-04-01), Renken et al.
patent: 3758386 (1973-09-01), Chan
patent: 4239737 (1980-12-01), Ermini
patent: 4364807 (1982-12-01), Ropentck et al.
patent: 4379037 (1983-04-01), Bolton et al.
Partington, Textbook of Inorganic Chemistry, 6th Edition, 1950, p. 467.

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