Process for reducing the fluorine content of hydrofluorocarbons

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570170, 570176, C07C 1725

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055234984

ABSTRACT:
The fluorine content of an acyclic saturated compound of the formula C.sub.n F.sub.a X.sub.b H.sub.c (wherein each X is independently selected from the group consisting of Cl and Br, and wherein n is 1 to 6, a is 1 to 13, b is 0 to 12, c is 1 to 9, and a+b+c equals 2n+2) is reduced by reacting the acyclic saturated compound with HCl in the vapor phase at an elevated temperature in the presence of a catalyst, the mole ratio of HCl to the acyclic saturated compound being at least about 1:1.

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Vecchio et al., J. Fluorine Chemistry, 4, 117-139, 1974.

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