Process for reducing nitrogen oxides

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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4232135, B01J 802

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active

055431240

ABSTRACT:
A process for efficiently reducing nitrogen oxides in exhaust gases including excess oxygen. The process includes intermittently introducing a reducing agent, such as hydrogen and carbon monoxide, for reducing nitrogen oxides to a reducing catalyst, such as platinum, disposed in an exhaust gas passage while maintaining an oxygen excess condition. The reducing agent is intermittently introduced in a manner to satisfy the following equation:
[NO.sub.x ]<[H.sub.2 ]+[CO], wherein [H.sub.2 ], [CO] and [NO.sub.x ] are molar concentrations of hydrogen, carbon monoxide and nitrogen oxides, respectively. The reducing catalyst may include a transition metal, an alkaline metal and/or an alkaline earth metal.

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