Compositions – Radioactive compositions
Patent
1990-07-25
1991-12-03
Hunt, Brooks H.
Compositions
Radioactive compositions
252631, 204 15, G21F 900
Patent
active
050698273
ABSTRACT:
A process for reducing and dissolving PuO.sub.2 comprises contacting the plutonium dioxide with a hydrazine-free, acid aqueous solution containing a reducing agent, whose redox potential is below +0.5 V/ENH in order to reduce and dissolve the plutonium. The reducing agent can be Cr.sup.2+ or U.sup.4+.
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V. T. Marchenko et al., Kinetics of the Reaction of Plutonium Ions with Tetravalent Uranium in Nitric Acid Solution, pp. 479-484, Jul. 1974.
T. W. Newton et al., The Kinetics of the Reaction Between Pu(IV) and Fe(II), pp. 244-247, Aug. 1959.
Cleveland, J. M. The Chemistry of Plutonium, 1970, pp. 47-58.
Koehly Gerard
Machuron-Mandard Xavier
Madic Charles
Commissariat a l''Energie Atomique
Hunt Brooks H.
Mai Ngoclan T.
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