Process for recovering vanadium accumulated on spent catalyst

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252411R, 252412, 252413, 423 62, 423492, B01J 2390, B01J 2392

Patent

active

042161185

ABSTRACT:
This invention relates to a process for selectively recovering vanadium from spent catalysts which were used in hydrodesulufurization, hydrodemetallization, etc. of heavy oils until metals in said heavy oils accumulated thereon. More particularly, it relates to a process for recovering vanadium, and if desired, vanadium along with nickel from spent catalysts in such a way that said spent catalysts are chlorinated with chlorinating agent(s) at a temperature below 600.degree. C. without being subjected to calcination so as to convert almost all the vanadium compounds to vanadium tetrachloride which is recovered in the form of a gas, including the chlorination of nickel compounds of nickel chloride which can also be recovered as such by solvent extraction.

REFERENCES:
patent: 3122510 (1964-02-01), Burk, Jr. et al.
patent: 3395974 (1968-08-01), Swimton
patent: 3494728 (1970-02-01), Letson
patent: 4013546 (1977-03-01), Suggitt et al.
patent: 4101444 (1978-07-01), Burk et al.

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