Process for recovering valuable metal from waste catalyst

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

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4231502, 4236585, 423144, 423114, 423 56, 423 58, 423 63, 423 68, 423132, 502 24, B01D 1100, C01G 3900, C01G 3100, C22B 2300

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054318920

ABSTRACT:
A process for recovering valuable metals from a waste catalyst based on an alumina carrier includes (a) roasting the waste catalyst at a temperature range of 400.degree. to 1,000.degree. C. to obtain a roasted product; (b) preparing a reduction dissolution by dissolving the roasted product with sulfuric acid in the presence of a metal as a dissolution catalyst; (c) separating a large part of the aluminum from the reduction dissolution solution and recovering aluminum as ammonium aluminum sulfate from the solution, optionally after subjecting the reduction dissolution solution to a treatment of removing iron; (d) extracting molybdenum as a molybdate by solvent extraction from the solution after separating and recovering aluminum from the solution; (e) extracting vanadium as a vanadate by solvent extraction from the solution obtained as a residue after extracting molybdenum; and (f) recovering nickel and cobalt each as a hydroxide from the extraction residue after recovering vanadium.

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