Process for recovering silver from photographic chemical effluen

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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521 25, 521 30, 527312, 210670, 210679, 210681, 210683, 210688, 210690, 210691, 528341, 528342, 106168, C08L 1100, C08J 520, B01D 1500, C08C 6926

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052946525

ABSTRACT:
A process for absorbing silver from photographic hypo solutions involves passing the hypo solution through a bed consisting of a multitude of a sponge product confined within a vessel. The sponge product is derived from an open-celled cellulosic sponge into which there has been incorporated 30% to 80% by weight of a polymer produced by the thermal interaction of polyethyleneimine (PEI) with a polycarboxylic acid. The polymer further contains an activating multivalent cation and between 90% and 300% water. Silver is eluted from the sponge product employing aqueous solutions of a complexing agent such as an ammonium compound or a cyanide compound. Following a water wash, the bed of sponge product is ready for its next cycle of silver absorption.

REFERENCES:
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patent: 3715339 (1973-02-01), Rainer
patent: 4287031 (1981-09-01), Good et al.
patent: 4332916 (1982-06-01), Thill
patent: 5002984 (1991-03-01), Rainer
patent: 5096946 (1992-03-01), Rainer
patent: 5162404 (1992-11-01), Rainer
patent: 5169883 (1992-12-01), Rainer

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