Process for recovering organic hydroxides from waste solutions

Chemistry: electrical and wave energy – Processes and products – Electrophoresis or electro-osmosis processes and electrolyte...

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204522, 204530, 204537, 205703, B01D 6144, B01D 1706

Patent

active

059102373

ABSTRACT:
In one embodiment, the present invention relates to a process for recovering organic hydroxide from contaminated solutions containing the organic hydroxide and impurities including charging the contaminated solution to a first electrochemical cell containing at least two compartments, a cathode, an anode and a size selective divider and passing a current through the first electrochemical cell whereby impurities migrate through the size selective divider; recovering a second solution containing organic ions from the first electrochemical cell and charging the second solution to a second electrochemical cell containing at least two compartments, a cathode, an anode and a divider and passing a current through the second electrochemical cell whereby the organic hydroxide is purified; and recovering the organic hydroxide from the second electrochemical cell. In another embodiment, the present invention relates to a process for recovering onium hydroxide from contaminated solutions containing the onium hydroxide and impurities including forming a first solution containing an onium salt and impurities from the contaminated solution; contacting the first solution with a size selective membrane under pressure, wherein at least a portion of the impurities pass through the size selective membrane thereby providing a second solution containing an onium salt and a decreased amount of impurities; charging the second solution to an electrochemical cell containing at least two compartments, a cathode, an anode and a divider and passing a current through the cell whereby the onium hydroxide is purified; and recovering the onium hydroxide from the cell.

REFERENCES:
patent: 4714530 (1987-12-01), Hale et al.
patent: 4931155 (1990-06-01), Dutcher et al.
patent: 5316679 (1994-05-01), Bruening
patent: 5354434 (1994-10-01), Satoh et al.
patent: 5389211 (1995-02-01), Sharifian et al.
patent: 5405508 (1995-04-01), Kawakami et al.
International Search Report for PCT Patent Application Serial No. PCT/US98/02344 mailed Jun. 23, 1998.

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