Process for recovering caprolactam from aqueous caprolactam...

Distillation: processes – separatory – With chemical reaction – Including step of adding catalyst or reacting material

Reexamination Certificate

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C159S047100, C203S014000, C203S029000, C203S091000, C540S540000

Reexamination Certificate

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07615137

ABSTRACT:
A continuous process is provided for recovering caprolactam from aqueous caprolactam product which includes (i) caprolactam, (ii) impurities, and (iii) water by (a) adding alkali hydroxide to the aqueous caprolactam product, in an amount of not more than 100 mmol alkali hydroxide per kg of caprolactam; (b) reacting at least part of the added alkali hydroxide to form alkali amino caproate, to obtain a caproate-enriched caprolactam product; and (c) distilling the caproate-enriched caprolactam product at reduced pressure.

REFERENCES:
patent: 4720328 (1988-01-01), Corbin et al.
patent: 4892624 (1990-01-01), Fuchs
patent: 5496941 (1996-03-01), Ritz et al.
patent: 5700358 (1997-12-01), Fuchs et al.
patent: 2005/0029086 (2005-02-01), Groot Zevert et al.
patent: 202 870 (1983-10-01), None
Publication 1: Japanese Patent Application Laid-Open No. 7-330720, Dec. 19, 1995 (D1).
Publication 2: Kagaku Jiten by Tokyo Kagaku Dojin, 3rdEd., Oct. 1, 2994 (D2).

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