Process for reactive esterification distillation

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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Reexamination Certificate

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07667068

ABSTRACT:
A process for producing organic acid di- or tri-esters, particularly citric acid tri-esters, with the available acid groups esterified using countercurrent reactive distillation using acid catalysts in a structured packing is described. In the reactive distillation an organic acid di- or tri-ester is formed by chemical reaction and purified to its final state within the single column. Organic acid di- or tri-esters are produced at relatively low cost, with less waste production in by-products of the reaction, and in a less complicated manner than prior processes. Organic acid di- and tri-esters have uses as solvents, as plasticizers and in conversion products.

REFERENCES:
patent: 1400849 (1921-12-01), Backhaus
patent: 2551625 (1951-05-01), Morrell et al.
patent: 2575243 (1951-11-01), Carlson et al.
patent: 2587753 (1952-03-01), O'Connor et al.
patent: 4435595 (1984-03-01), Agreda et al.
patent: 5008046 (1991-04-01), Bremus et al.
patent: 5536856 (1996-07-01), Harrison et al.
patent: 5719311 (1998-02-01), Wu et al.
patent: 6045703 (2000-04-01), Miller
patent: 6586609 (2003-07-01), Ruggieri et al.
patent: 6815525 (2004-11-01), DeBruin
patent: 7045100 (2006-05-01), Ergun et al.
patent: 2006/0014977 (2006-01-01), Miller et al.
patent: 2007/0129565 (2007-06-01), Sutton et al.
patent: 1294371 (1972-10-01), None
patent: WO9851657 (1998-11-01), None
Nong, L., et al., Synthesis of Tributyl Citrate with Aluminum PHosphotungstate Supported on activated Carbon, Jingxi Huagong Zhongjianti (2004), 34(3), 50-52, 54. (Abstract).
Shi, et al. , Synthesis of tributyl citrate catalyzed by solid superacid S2082-/Ti02-Si02, Yingyong Huagong (2004), 33(3), 41-43. (Abstract).
Zheng et al., Synthesis of tributyl citrate catalyzed by tetrabutyl titanate, Jingxi Huagong Zhongjianti (2004), 34(1), 28-30. (Abstract).
Asthana et al., Org. Process Res. & Dev., 9, 599-607 (2005).
Deng et al., The synthesis of tributyl citrate catalyzed by sodium hydrogen sulfate, Jingxi Huagong Zhongjianti (2003), 33(6), 49-50. (Abstract).
Gangadwala et al., Ind. Eng. Chem. Res. 42 2146-2155 (2003).
Liu et al., Catalytic synthesis of tri-butyl citrate with dealuminated USY zeolite, Hecheng Huaxue (2003), 11(2), 175-177. (Abstract).
Van Baten et al Catalysis Today, 69, 371-377 (2001).
Gotze et al., Catalysis Today., 69, 201-208 (2001).
Smejkal et al., Chem. Eng. Sci., 56, 365-370 (2001).
Ratheesh and Kannan., Chem. Eng. J., 104, 45-54 (2004).
Kolodziej et al., Chem. Eng. Proc., 43, 457-464 (2004).
Schmitt et al., Chem. Eng. Proc., 43, 397-409 (2004).
Schmitt et al., Chem. Eng. Proc., 44, 677-685 (2005).
Bock et al., Chem. Eng. Prog. 36, 101-109 (1997).
Omota et al., Chem. Eng. Sci., 58, 3159-3174 (2003).
Tao, X., Huazue Shijie, 39(6), 302-304 (1998). (Abstract).
Asthana, Navinchandra et al., Reactive Distillation for the BioRefinery:Production of Organic Acid Esters, Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem. 2005, 50(2), (XP008089894)p. 683-684.
Choi, Jong et al., Reaction Kinetics of Lactic Acid with Methanol Catalyzed by Acid Resins, International Journal of Chemical Kinetics, (XP-001057571)vol. 28, 37-41 (1996).
EP 05760216 (PCT/US2005021742)Supplementary European Search Report.
Sharma, M. M., Mahajani, S.M. Industrial Application of Reactive Distillation in Reactive Distillation Edited by Sundmacher K. and Kienle A., Wiley VCH, Germany, 1 (2003).
Taylor, R., et al., Modelling Reactive Distillation. Chem. Eng. Sci., 55, 5183 (2000).
Modeling of Homogeneous and heterogeneous Reactive Distillation Processes, Chapter 9 in “Reactive Distillation” Editors: K. Sundmacher, A. Kienle, pp. 217-240, Wiley-VCH, Mannheim (2003).
Hiwale, R.S., et al., Industrial Applications of Reactive Distillation: Recent Trends. Int. J. of Chem. React. Eng., 2, Review R1 (2004).
Spes, H., Catalytic reactions in ion-exchange columns under conditions of the chemical equilibrium shift. WackerChem.Werk, Burghausen, Ger., Germany. Chemiker-Zeitung (1966), 90(13), 443-446. (Abstract).
Stankiewicz and Moulijn, 2000.
Moritz and Hasse, (Chem. Eng. Sci. 54, 1367-1374 (1999).
Hanika et al., (Chem. Eng. Sci. 54, 5205-5209 (1999).

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