Process for purifying polyisocyanates and the polyisocyanates th

Organic compounds -- part of the class 532-570 series – Organic compounds – Isocyanate esters

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C07C14300

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active

047743573

ABSTRACT:
Crude polyisocyanates are purified by extraction at a temperature from 80.degree. to 180.degree. C. to form a two-phase system. The phases are separated and the phase made up of purified polyisocyanate and solvent is cooled to a temperature which is at least 50.degree. C. below the extraction temperature. Upon cooling, a second two-phase system forms. Purified polyisocyanate containing residual solvent is recovered upon separation of these phases. Solvent in which polyisocyanate is present that is reclaimed during this process may be reused in subsequent extractions. The purified polyisocyanates have a viscosity which is lower than that of crude polyisocyanates having substantially the same isocyanate content and average functionality. These purified polyisocyanates are useful in the production of polyurethane foams and moldings as well as adhesives and coatings.

REFERENCES:
patent: 3144474 (1964-08-01), Kantyka et al.
patent: 3479384 (1969-11-01), Heiss
patent: 3816496 (1974-06-01), Schnabel
patent: 3987075 (1978-10-01), Schnabel

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