Process for purifying hydrofluoropropanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

Reexamination Certificate

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C502S185000, C502S313000, C502S355000, C570S177000

Reexamination Certificate

active

10734946

ABSTRACT:
A process is disclosed for purifying a hydrofluoropropane of undesirable C2–C4olefinic and C1–C4saturated chlorinated impurities, comprising the steps of: contacting a first mixture of hydrofluoropropane, olefinic impurity and saturated chlorinated impurity with hydrogen and hydrogen fluoride concurrently in the presence of a bifunctional catalyst, for example an alloy of gold and palladium supported on carbon, capable of catalyzing hydrogenation and fluorination. During the contacting step, olefinic impurity is converted to saturated hydrogenated derivative and/or saturated hydrofluorinated derivative, and saturated chlorinated impurity is converted to a saturated hydrodechlorinated derivative and/or saturated fluorinated derivative. The hydrofluoropropane thus formed is substantially free of both the olefinic and saturated chlorinated impurities and may be used as obtained or subject to further purification steps such as distillation to remove the process derivatives (e.g., hydrogenation, hydrodechlorination and hydrofluorination derivatives) from the hydrofluoropropane.

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patent: 5208396 (1993-05-01), Anton
patent: 5447896 (1995-09-01), Rao
patent: 5463152 (1995-10-01), Rao
patent: 5569797 (1996-10-01), Fu et al.
patent: 6147267 (2000-11-01), Sievert et al.

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