Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From fluorine-containing reactant
Patent
1996-08-08
1998-08-04
Truong, Duc
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From fluorine-containing reactant
528310, 528315, 528332, 528425, 528492, 528503, 568615, 568677, 568679, C08G 7324
Patent
active
057895341
ABSTRACT:
The purification process comprises removing carboxylic acids and/or carboxylic acid salts contained as impurities in a fluorinated polyether having at at least one end thereof a terminal vinyl group linked thereto through an amide group-containing linkage by heating, in the presence of an amine compound such as triethylamine and dimethylaminotrimethylsilane, the fluorinated polyether containing said impurities or a reaction mixture obtained after the completion of reaction in a process of producing said fluorinated polyether. According to the purification process, the impurities can be easily removed from said fluorinated polyether. When the thus purified fluorinated polyether is used as a starting material for an addition type curable composition together with a SiH group-containing organosilicon compound, a liquid rubber material excellent in curability and storage stability can be obtained. Further, when the purified product is used as a starting material for hydrosilylation reaction, improvements in yield and reaction rate are expected.
REFERENCES:
Chem Abstract, vol. 122, 1995: 122:242059 "Fluorine containing organic silicon compounds" Takashi et al., p. 121.
122 : 267861 "Room temperature curable, acid-, alkali-, heat-, and solvent-resistant perfluoro polyether-polyamide-siloxane compositions"shinichi et al, p. 137.
Koike Noriyuki
Matsuda Takashi
Sato Shin'ichi
Shin-Etsu Chemical Co. , Ltd.
Truong Duc
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