Process for purifying a fluorinated polyether having at an end t

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From fluorine-containing reactant

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528310, 528315, 528332, 528425, 528492, 528503, 568615, 568677, 568679, C08G 7324

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057895341

ABSTRACT:
The purification process comprises removing carboxylic acids and/or carboxylic acid salts contained as impurities in a fluorinated polyether having at at least one end thereof a terminal vinyl group linked thereto through an amide group-containing linkage by heating, in the presence of an amine compound such as triethylamine and dimethylaminotrimethylsilane, the fluorinated polyether containing said impurities or a reaction mixture obtained after the completion of reaction in a process of producing said fluorinated polyether. According to the purification process, the impurities can be easily removed from said fluorinated polyether. When the thus purified fluorinated polyether is used as a starting material for an addition type curable composition together with a SiH group-containing organosilicon compound, a liquid rubber material excellent in curability and storage stability can be obtained. Further, when the purified product is used as a starting material for hydrosilylation reaction, improvements in yield and reaction rate are expected.

REFERENCES:
Chem Abstract, vol. 122, 1995: 122:242059 "Fluorine containing organic silicon compounds" Takashi et al., p. 121.
122 : 267861 "Room temperature curable, acid-, alkali-, heat-, and solvent-resistant perfluoro polyether-polyamide-siloxane compositions"shinichi et al, p. 137.

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