Process for production of synthesis gas with reduced sulfur cont

Compositions – Gaseous compositions – Carbon-oxide and hydrogen containing

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48197R, C01B 322, C01B 302

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active

048511510

ABSTRACT:
A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

REFERENCES:
patent: 4788003 (1988-11-01), Najjar et al.

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