Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1996-04-17
1997-12-23
Grumbling, Matthew V.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
548552, 560157, 564215, C07D26304
Patent
active
057009465
ABSTRACT:
The present invention provides a process for producing an N-vinyl compound, which comprises subjecting an N-(-alkoxyalkyl) compound to gas phase intramolecular alcohol elimination to convert said compound to an N-vinyl compound directly in one step, wherein a solid oxide containing phosphorus and an alkali metal and/or an alkaline earth metal is used as a catalyst. This process need not use any solvent or any auxiliary raw material and consequently can produce an N-vinyl compound simply and safely without generating any waste material derived from the auxiliary raw material.
REFERENCES:
patent: 2592254 (1952-04-01), Dickey
patent: 2905690 (1959-09-01), Bakke
patent: 3019231 (1962-01-01), Peppel et al.
patent: 3033829 (1962-05-01), Bakke
patent: 3336369 (1967-08-01), Schwiersch et al.
patent: 3346586 (1967-10-01), Ingleby
patent: 4322271 (1982-03-01), Jensen et al.
patent: 4511722 (1985-04-01), Krimm et al.
patent: 4574159 (1986-03-01), Hassdenteufel
patent: 4831153 (1989-05-01), Phung
patent: 5059713 (1991-10-01), Armor et al.
patent: 5233077 (1993-08-01), Waller
patent: 5410070 (1995-04-01), Franz et al.
Furukawa, et al. "Reaction of Vinyl Ethers with . . . ", J. Org. Chem., 23, 672-675 (1958).
Akashi, et al, "A Novel Synthetic Procedure . . . ", J. Polm. Sci: Part A: Poly. Chem. 28, 3487-3497 (1990).
Stackman, et al., "Synthesis of N-Vinylacetamide . . . ", Ind. Eng. Chem. Prod. Res. Dev. 1985, 24, 242-246.
Kutner, A., "Preparation, Properties and . . . " J. Org. Chem., 26, 3495-3497 (1961).
Drechsel, E.K., "N-Vinyl-2-oxazolidone", J. Org. Chem., 22 849-851 (1957).
Zhang, et al, "Synthesis of N-vinyl-N-methylcarbamic . . . ", Huaxue Shijie 1987, 28(1), 10-13 (CA 106:157261 r).
Kanbe Hideyuki
Kurusu Akira
Shimasaki Yuuji
Bucknum Michael
Grumbling Matthew V.
Nippon Shokubai Co. , Ltd.
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