Process for production of dimethyltetralin

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585320, 585410, C07C 522

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active

053960084

ABSTRACT:
There is disclosed a process for producing dimethyltetralin consisting of 1,5-, 1,6- and 2,6-dimethyltetralin which comprises cyclizing 5-tolyl-penta-2-ene in gaseous state in the presence of diluent by the use of a catalyst comprising a crystalline aluminosilicate and a carrier and optionally a molding assistant. The abovementioned process is capable of producing industrially useful dimethyltetralin as the starting raw material for dimethylnaphthalene with high yield and high selectivity with minimized side reactions over a long stabilized period.

REFERENCES:
patent: 3775496 (1973-11-01), Thompson
patent: 4950825 (1990-08-01), Sikkenga et al.
patent: 5008479 (1991-04-01), Abe et al.
patent: 5030701 (1991-07-01), Sikkenga et al.
Chemical Abstracts, vol. 80, No. 17, 29 Apr. 1974, abstract No. 95601k, p. 382, of JP-A-396,577.
Chemical Abstracts, vol. 83, No. 23, 8 Dec. 1975, abstract No. 192938v, p. 427, of JP-A-593,956.

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