Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-06-16
1976-08-10
Brust, Joseph P.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
C07C12004, C07C12146
Patent
active
039741990
ABSTRACT:
Cyclopropylcyanide is prepared by an improved process comprising reacting by contacting a .gamma.-halo-butyronitrile or mixture thereof, with an alkali metal hydroxide in the presence of a catalytic amount of an onium salt. For example, the reaction of 4-chlorobutyronitrile with sodium hydroxide in the presence of benzyltriethylammonium chloride produces cyclopropylcyanide in high yield.
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Schlatter, J. Org. Syn., Coll. 3, pp. 223-225, 1955.
Cloke, et al., J.A.C.S., 53, 1931, pp. 2791-2796.
Pews R. Garth
Plonka James H.
Brust Joseph P.
Plotecher Gary R.
The Dow Chemical Company
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