Process for production of artificial leathers having air permeab

Adhesive bonding and miscellaneous chemical manufacture – Methods – Surface bonding and/or assembly therefor

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156246, 156344, 260 25AY, 264 463, 264 54, 264257, 264DIG5, B29D 2704, B32B 520, B32B 3114

Patent

active

039590496

ABSTRACT:
A process for the production of artificial leathers having excellent air permeability and resembling a natural leather is provided, which comprises incorporating a catalyst, a foam stabilizer and, optionally, a pigment and other additive into an isocyanate-terminated polyurethane prepolymer formed by compounding a polyester diol derived from an aliphatic dicarboxylic acid with an organic polyisocyanate so that the [NCO]/[OH] ratio is within a range of from 2.0 to 4.0, to thereby form a substantially solvent-free paint having a viscosity adjusted to 70 to 1000 poises, coating the paint on a release paper in an amount of 50 to 400 g/m.sup.2, applying the release paper to a substrate, allowing foaming and polymerization reactions to proceed in an atmosphere of a dry-bulb temperature of 40.degree. to 95.degree.C. and a relative humidity of at least 60%, passing the assembly, during the advance of said reactions, between two upper and lower rolls, the clearance of which is so adjusted that the foaming ratio is 2 to 4 in a polyurethane foam layer formed from the polyurethane prepolymer paint coating, further advancing the reactions, and peeling the release paper from the foam layer.

REFERENCES:
patent: 2764565 (1956-09-01), Hoppe et al.
patent: 2850467 (1958-09-01), Livingood
patent: 2956310 (1960-10-01), Roop et al.
patent: 3000757 (1961-09-01), Johnston et al.
patent: 3047449 (1962-07-01), Coble
patent: 3694530 (1972-09-01), Wolfe
patent: 3830760 (1974-08-01), Bengtson

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