Process for production of allyl carboxylate

Details Process for production of allyl carboxylate Process for production of allyl carboxylate

1985-01-25

1986-01-28

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502170, C07C 6705

Patent

active

045672920

ABSTRACT:
A process for producing an allyl carboxylate comprising the step of reacting propylene, oxygen or oxygen-containing gas, and a lower saturated carboxylic acid in the presence of a catalyst at a temperature of 100.degree. C. to 300.degree. C. and a pressure of 0 to 30 atm (gauge) in a vapor phase. The catalyst is prepared by supporting, on a carrier, at least one alkali metal acetate and at least one bivalent palladium salt in the presence of: (A) at least one organic base selected from the group consisting of (i) aliphatic amines having the formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 may be the same or different and represent hydrogen, or an alkyl group having 1 to 10 carbon atoms or benzyl group optionally substituted with --CN, --OR, --COOR, or a --N(R).sub.2 group wherein R is H or an alkyl group having 1 to 3 carbon atoms, or any two groups of R.sup.1, R.sup.2, and R.sup.3 may together form a ring provided that R.sup.1, R.sup.2, and R.sup.3 are not simultaneously hydrogen; (ii) aromatic amines having the formula: ##STR2## wherein X represent --R, --CN, --OR, --COOR, --NO.sub.2, or --N(R).sub.2 wherein R is the same as defined above, R.sup.2 and R.sup.3 are the same as defined above; and (iii) nitrogen-containing cyclic compounds having the formula: ##STR3## wherein X is the same as defined above; and/or (B) at least one carboxylic acid having the formula:

REFERENCES:
patent: 3417133 (1968-12-01), Harris
patent: 3609180 (1971-09-01), Shigematsu
patent: 4365082 (1982-12-01), Laloz

Affiliated with

Also associated with

Rating

Process for production of allyl carboxylate does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for production of allyl carboxylate, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for production of allyl carboxylate will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1307126