Process for production of acrylic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 5132

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052181464

ABSTRACT:
A process for the production of acrylic acid by the two-stage catalytic vapor-phase oxidation of propylene with molecular oxygen, the first stage for oxidizing propylene to produce mainly acrolein and the second stage for oxidizing acrolein to produce mainly acrylic acid, which process comprises supplying to the first-stage reaction a raw gas containing a saturated aliphatic hydrocarbon having 1 to 5 carbon atoms in an amount in the range of 5 to 70% by volume, carbon dioxide in an amount in the range of 3 to 50% by volume, and the aliphatic hydrocarbon and the carbon dioxide in a total amount in the range of 20 to 80% by volume and further containing steam in an amount in the range of 0.5 to 8 mol per mol of propylene.

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