Process for production antibiotic A53868

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Using tissue cell culture to make a protein or polypeptide

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C12P 2102, C12N 120, C12R 1465

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active

044630921

ABSTRACT:
Antibiotic A53868 factor A, which is N.sup.2 -glycyl-N-(2-methylene-2-phosphonoethyl)leucinamide, and the formula: ##STR1## and the salts thereof, which are useful as antibiotics or as intermediates to antibiotics; methods of preparing A53868 factor A by fermentation of Streptomyces luridus; and the microorganism S. luridus NRRL 15101.

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Derwent Abstract No. 06762E/04 (Grelan Pharmaceutical) of Japanese Unexamined Application No. J5 6161-397 (Dec. 11, 1981).
L. Maier, "Advances in the Chemistry of Aminophosphinic Acids", Phosphorous and Sulfur, 14, 295-296 and 320-321 (1983).
F. Atherton et al., "Phosphonopeptides as Antibacterial Agents: Rationale, Chemistry, and Structure-Activity Relationships", Antimicrob. Agents and Chemotherapy 15 (5), 677-683 (1979).
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F. Hahn, "Alafosfalin, A New Synthetic Antibacterial Compound", Naturwissenschaften 68, 90 (1981).
B. Park et al., "Structure of Plumbemycin A and B, Antagonists of L-Threonine from Streptomyces plumbeus", Agric. Biol. Chem. 41 (3), 573-575 (1977).
F. Atherton et al., "Phosphonopeptide Antibacterial Agents Related to Alafosfalin: Design, Synthesis and Structure-Activity Relationships", Antimicrobial Agents and Chemotherapy 18 (6), 897-905 (1980).
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Derwent No. 46673 D/26 (Grelan Pharmaceutical) of Japanese Unexamined Patent No. J5 6051-494 (May 9, 1981).
M. Okuhara et al., "New Phosphonic Acid Antibiotics Produced by Strains of Streptomyces", Drugs Exptl. Clin. Res., 7 (4), 559-564 (1981).
Y. Okada et al, "Amino Acids and Peptides v. Synthesis of N-L- and D-Alanyl-1-Amino-Ethylphosphinic Acids", Chem. Pharm. Bull. 28 (4), 1320-1323 (1980).
K. Hemmi et al., "Studies on Phosphonic Acid Antibiotics. IV. Synthesis and Antibacterial Activity of Analogs of 3-(N-Acetyl-N-Hydroxyamino)Propylphosphinic Acid (FR-900098)", Ibid, 30 (1), 111-118 (1982).

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