Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1998-09-22
2000-08-29
Geist, Gary
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
C07C 6934
Patent
active
061111341
ABSTRACT:
A method for production of unsaturated glycol diester, such as 1,4-diacetoxy-2-butene, is formed of reacting conjugated diene with carboxylic acid and molecular oxygen in the presence of a solid catalyst in the liquid phase under pressure. The catalyst is formed of rhodium and tellurium, which are supported on an inorganic porous carrier. The catalyst is stable, and the unsaturated glycol diester is prepared in high conversion and selectivity.
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Patent Abstracts of Japan, vol. 002, No. 081 (C-016), Jun. 28, 1978 & JP 53 037609 A (Mitsui Toatsu Chem Inc.) Apr. 6, 1978.
Patent Abstracts of Japan, vol. 001, No. 149 (C-031), Nov. 30, 1977 & JP 52 091817 A (Sumitomo Chem Co., Ltd.) Aug. 2, 1977.
Database WPI, Section ch, week 7712, Derwent Publications Ltd., London, GB, Class E15, AN 77-20834Y, XP002089369 & JP 52 017422 A (Mitsubishi Chem Ind Ltd) Feb. 9, 1977.
Hara Yoshinori
Kusaka Haruhiko
Ohno Hironobu
Okuda Masami
Deemie Robert W.
Geist Gary
Mitsubishi Chemical Corporation
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