Process for producing trialkali metal aluminum hexahydride

Details Process for producing trialkali metal aluminum hexahydride Process for producing trialkali metal aluminum hexahydride

1974-11-20

1977-03-01

Sneed, Helen M. S.

Chemistry of inorganic compounds

Hydrogen or compound thereof

260448A, C01B 604

Patent

active

040102483

ABSTRACT:
This invention relates to the preparation of alkali metal aluminum dihydrocarbon dihydrides and in particular to such compounds of sodium, potssium or lithium having hydrocarbon radicals containing from 2 to about 30 carbon atoms per radical. Such dihydrocarbon materials, as typified by sodium aluminum diethyl dihydride, and by the potassium or lithium counterparts, either singly or in mixtures with respect to alkali metals and hydrocarbon groups, are soluble and useful in inert aromatic hydrocarbon solvents and have excellent mild reducing properties for various functional groups such as carbonyl groups in various organic compounds.

REFERENCES:
patent: 2786860 (1957-03-01), Ziegler et al.
patent: 2915542 (1959-12-01), Robinson et al.
patent: 3098706 (1963-07-01), Blitzer et al.
patent: 3143542 (1964-08-01), Ziegler et al.
patent: 3686248 (1972-08-01), Nelson
Chemical Abstracts, v67, 70140c (1967).
Ashby et al., Inorganic Chemistry v2 pp. 499-504 (1963).
Ashby et al., Inorganic Chemitry v5, pp. 1615-1617 (1966).
Chemical Abstracts, v64, 13803b (1966).

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