Process for producing thioalkyl or thioarylphenones

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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C07C31912

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049946234

ABSTRACT:
Thiophenones are produced by acylating the aromatic ring of thiophenolic ethers in the presence of anhydrous hydrofluoric acid. It has been found that if the thio group is in the form of a thioether and not a thiol, the aromatic ring can be acylated to form the thiophenone in the presence of anhydrous hydrofluoric acid.

REFERENCES:
patent: 2833825 (1958-05-01), Lewis
patent: 4082807 (1978-04-01), Eiglmeier
patent: 4453012 (1984-06-01), Desbois
patent: 4474990 (1984-10-01), Jansons
patent: 4560789 (1985-12-01), Davenport et al.
patent: 4568763 (1986-02-01), Davenport et al.
patent: 4593125 (1986-06-01), Davenport et al.
patent: 4607125 (1986-08-01), Mott
patent: 4618726 (1986-10-01), Desbois
patent: 4670603 (1987-06-01), Piccolo et al.
patent: 4894482 (1990-01-01), Lindley et al.
"New Photoinitiators for Pigmented Systems", Technical Paper, FC 84-989, Society of Manufacturing Engineers, 1984, pp. 1-22.
Dann and Mylius, Annalen der Chemie, 587, Band, 1-15, W. Germany, 1954.
"Hydrogen Fluoride as a Condensing Agent. VII. The Acylation of Aromatic Compounds", Journal of the American Chemical Society, vol. 1, 61, Jul. 1939.
Modern Synthetic Reactions, Herbert O. House, W. A. Benjamin, Inc., Publishers, 1972, p. 9.
Advanced Organic Chemistry, Second Edition, Jerry March, McGraww-Hill Book Co., pp. 466 and 1104.

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