Process for producing sulfonylbis (phthalic anhydride)

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549248, 562412, 562413, 562414, C07D30783

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active

053429680

ABSTRACT:
A process for making relatively high purity eulfonylbis(phthalic anhydride) is provided. 3,3',4,4'-tetramethyl diphenyl sulfone is catalytically oxidized in a solvent under liquid phase elevated temperature and pressure conditions. The catalyst is constituted by cobalt, manganese, zirconium, and bromine. Sulfonylbis(phthalic) acid is recovered by crystallization and is then heated to produce the anhydride. Preferably, the acid is purified prior to dehydration.

REFERENCES:
patent: 3022320 (1962-02-01), Woodbury et al.
patent: 3920735 (1975-11-01), Wampfler et al.

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