Process for producing sodium carbonate from complex brines

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkali metal

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423190, 423422, 423426, 423427, C01D 700, C01D 737

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active

042910021

ABSTRACT:
A process for the production of sodium carbonate wherein sodium bicarbonate is recovered from a brine containing sodium carbonate by carbonation of the brine under controlled conditions. The sodium bicarbonate is crystallized from the carbonated brine in a multi-stage carbonating, cooling and crystallization process after which it is filtered to produce wet cake. The wet cake is subjected to predrying to provide a predried wet cake of a specified free moisture content and mixed with recycle light ash to provide a dryer feed of specified moisture content to alleviate problems of product fouling or plugging of the dryer. The light ash from the dryer then is bleached and subjected to recrystallization, screening, centrifuging and drying to provide a dried sodium carbonate possessing, after evaporation of the water of hydration and free moisture, less than 0.10 percent moisture and chemical and physical properties meeting commercial dense ash specifications.

REFERENCES:
patent: 1865833 (1932-07-01), Chesny
patent: 2693403 (1954-11-01), Brumbaugh et al.
patent: 2962348 (1960-11-01), Seglin et al.
patent: 3028215 (1962-04-01), Frint
patent: 3188170 (1965-06-01), Mantz et al.
patent: 3717698 (1973-02-01), Ilardi et al.
patent: 3900292 (1975-08-01), Fairchild
Manufacture of Soda by Te-Pang Hou, Ph.D., Reinhold Publishing Corporation (1942), pp. 173-179.

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