Process for producing quinones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260385, C07C 4966, C07C 4968

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active

039534820

ABSTRACT:
A process for producing quinones corresponding to anthracenes or alkylnaphthalenes in high yields and selectivities, which comprises reacting the anthracenes or alkylnaphthalenes with hydrogen peroxide in the liquid phase in the presence of hydrogen chloride as a catalyst. Methanol, for example, may be used as a reaction medium.

REFERENCES:
patent: 2373003 (1945-04-01), Arnold
patent: 2395638 (1946-02-01), Milas
Arnold et al., Journal of Organic Chemistry, Vol. 5, pp. 250-252 (1940).
Charrier et al., Chemical Abstracts, Vol. 22, pp. 768 & 769 (1928).
Solyanikov et al., Chemical Abstracts, Vol. 70, 118553f (1969).
Hatcher et al., Chemical Abstracts, Vol. 18, p. 931 (1924).
Milas, Journal of the American Chemical Society, Vol. 59, pp. 2342-2344 (1937).
Oda et al., Chemical Abstracts, Vol. 54, 16369h (1960).
Tsutsumi, Chemical Abstracts, Vol. 54, 21543g (1960).

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