Process for producing polyfluoroalkyl ester of unsaturated...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C560S223000

Reexamination Certificate

active

07135592

ABSTRACT:
A polyfluoroalkyl ester of unsaturated carboxylic acid is produced in high yield in a more simple reactor and with much more reduction in the waste than the conventional process based on esterification reaction by subjecting a polyfluoroalkanol represented by the following general formula:in-line-formulae description="In-line Formulae" end="lead"?Rf—R—OHin-line-formulae description="In-line Formulae" end="tail"?where Rf is a polyfluoroalkyl group having 1–6 carbon atoms and R is an alkylene group having 1–6 carbon atoms, and an unsaturated carboxylic acid to dehydration reaction in a fluorine-containing solvent in the presence of an acid catalyst and a polymerization inhibitor.

REFERENCES:
patent: 1266408 (1972-03-01), None
patent: 59-181239 (1984-10-01), None
patent: 62-92914 (1986-10-01), None
patent: 63-210115 (1987-02-01), None
patent: 5-51417 (1991-08-01), None
Inhibition of Gap Junctional Intercellular Communication by Perfluorinated Fatty Acids is Dependent on the Chain Length of the Fluorinated Tail, Brad L. Upham, et al, Int. J. Cancer: 78, 491-495 (1998).

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