Process for producing polyethylene of ultrahigh molecular weight

Details Process for producing polyethylene of ultrahigh molecular weight Process for producing polyethylene of ultrahigh molecular weight

1989-01-26

1990-05-08

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526 90, 526 95, 526107, 526185, B01J 800

Patent

active

049239350

ABSTRACT:
A process for producing polyethylene of ultrahigh molecular weight having an intrinsic viscosity of 10-30 dl/g at 135.degree. C. in decalin is disclosed which comprises at least the following two stages of polymerization reaction: (a) a first reaction stage where in ethylene is polymerized with use of a catalyst comprising a solid component containing at least Mg, Ti and/or Va and in the absence or presence of hydrogen of reduced concentration to produce 70-99.5 weight parts of polyethylene having an intrinsic viscosity of 12-32 dl/g at 135.degree. C. in decalin; and (b) a second reaction stage wherein a fresh feed of ethylene is polymerized in the presence of hydrogen of higher concentration to produce 30-0.5 weight parts of polyethylene having an intrinsic viscosity of 0.1-5 dl/g at 135.degree. C. in decalin.

REFERENCES:
patent: 4786687 (1988-11-01), Sano et al.

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