Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1981-07-02
1983-08-09
Smith, Edward J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
252429B, 526128, 526153, 5263486, C08F 464, C08F 1008
Patent
active
043980066
ABSTRACT:
Butene-1 is polymerized in the presence of a catalytic system comprising a solid catalytic component (A), a trialkylaluminum compound (B), an organic acid ester (C), and an organoaluminum compound (D) at a molar ratio of (D) to (B) ranging 0.1 to 10 wherein said solid catalytic component (A) is obtained by reacting a reaction product (a) of a Grignard reagent with a chain or cyclic hydropolysiloxane having the unit ##EQU1## (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3) with at least one compound having the formula
REFERENCES:
patent: 4234710 (1980-11-01), Moberly et al.
patent: 4235984 (1980-11-01), Shiga et al.
patent: 4258167 (1981-03-01), Tsubaki et al.
patent: 4282114 (1981-08-01), Ito et al.
patent: 4290915 (1981-09-01), Toyota et al.
Abe Toyohiko
Koto Noriaki
Tsubaki Kazumi
Nissan Chemical Industries Ltd.
Smith Edward J.
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