Process for producing polyacetylene

Plastic and nonmetallic article shaping or treating: processes – Carbonizing to form article – Agglomeration or accretion

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264298, 427 36, 427 47, B29C 4102, C08F 3802

Patent

active

050193031

ABSTRACT:
The present invention concerns the fields of processes for producing an organic ultrathin film having polyacetylene linkages and the resultant films. In one embodiment the process for producing the film consists of the steps forming an acetylene monomolecular film on a water surface, applying magnetic or electric field to enhance orientation, irradiating the acetylene film with an energy beam to polymerize the acetylene film into a polyacetylene film. Other embodiments for producing the film consists of the steps of forming an acetylene film by chemical absorption, applying magnetic or electric field, and irradiating the film with an energy beam. The polymerized film is useful as an electrical material having high conductivity and as an optical material having non-linear effect.

REFERENCES:
patent: 4798740 (1989-01-01), Tomida et al.
Molecular Crystals and Liquid Crystals, vol. 96, 1983, pp. 109-120, Gordon and Breach Publishers, Inc., U.S.; C. Bubeck et al.: "Mechanisms of the Spectral Sensitization of the Diacetylene Polymerization".
Journal of Polymer Science: Polymer Letters Edition, vol. 16, 1978, pp. 205-210, John Wiley & Sons, Inc.; D. Day et al.: "Polymerization of Diacetylene Carbonic Acid Monolayers at the Gas-Water Interface".

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