Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1980-01-16
1984-08-21
Gerstl, Robert
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
562459, C07C 51337
Patent
active
044671121
ABSTRACT:
p-n-Alkylbenzoic acids having high purity without containing isomers are important as intermediates for liquid crystals. The p-n-alkylbenzoic acid is produced by reacting a p-formylbenzoic acid or its ester with a ketone having the formula ##STR1## wherein R represents a C.sub.1 -C.sub.18 n-alkyl or n-alkenyl group in the presence of a basic catalyst to obtain an unsaturated ketone compound having the formula ##STR2## wherein R is defined above and X represents hydrogen atom or a C.sub.1 -C.sub.6 alkyl group, and then, hydrogenating and reducing the unsaturated ketone compound to obtain the p-n-alkylbenzoic acid having the formula ##STR3##
REFERENCES:
Cran et al., Organic Chemistry 2nd ed., p. 567, (1962).
House, Modern Synthetic Reactions, pp. 173, 232-235, (1972).
Weygand et al., Preparative Organic Chemistry, pp. 32-36, 71-76, 986-987, (1972).
Horning et al., Org. Sym. 31, p. 56, (1951).
Wojcik et al., J.A.C.S. 56, 2424-2425, (1934).
Kusabe Kouji
Matsuura Ryo
Nagaoka Kazuya
Nakatani Shuichi
Gerstl Robert
Kawasaki Kasei Chemicals Ltd.
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